Phase equilibria at 1150°C in the Co-rich alloys SmCoZr and structure of the 1:7 phase
Identifieur interne : 000205 ( Maroc/Analysis ); précédent : 000204; suivant : 000206Phase equilibria at 1150°C in the Co-rich alloys SmCoZr and structure of the 1:7 phase
Auteurs : S. Derkaoui [Maroc] ; N. Valignat [France] ; C. H. Allibert [France]Source :
- Journal of Alloys and Compounds [ 0925-8388 ] ; 1996.
Descripteurs français
- Pascal (Inist)
English descriptors
- KwdEn :
Abstract
In the concentration range 75–100 at.% Co, the isothermal section at 1150°C of the system SmCoZr is determined experimentally. The following features are evidenced: a very small Sm solubility in Co, Zr2Co11, and Zr6Co23, an extended Zr for Sm substitution rate in SmCo3, Sm2Co7 and Sm5Co19, and a significant Zr solubility in SmCo5 and Sm2Co17 that induces the existence of a continuous ternary single phase 1:7. On the basis of the lattice parameter data, the formation of this phase by the substitution of Co dumbbells and/or Sm atoms for Zr atoms is proposed.
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DOI: 10.1016/0925-8388(95)02003-9
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<front><div type="abstract" xml:lang="en">In the concentration range 75–100 at.% Co, the isothermal section at 1150°C of the system SmCoZr is determined experimentally. The following features are evidenced: a very small Sm solubility in Co, Zr2Co11, and Zr6Co23, an extended Zr for Sm substitution rate in SmCo3, Sm2Co7 and Sm5Co19, and a significant Zr solubility in SmCo5 and Sm2Co17 that induces the existence of a continuous ternary single phase 1:7. On the basis of the lattice parameter data, the formation of this phase by the substitution of Co dumbbells and/or Sm atoms for Zr atoms is proposed.</div>
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